Improvements to the Overpotential of All-Solid-State Lithium-Ion Batteries during the Past Ten Years

After the research that shows that Li10GeP2S12 (LGPS)-type sulfide solid electrolytes can reach the high ionic conductivity at the room temperature, sulfide solid electrolytes have been intensively developed with regard to ionic conductivity and mechanical properties. As a result, an increasing volume of research has been conducted to employ all-solid-state lithium batteries in electric automobiles within the next five years. To achieve this goal, it is important to review the research over the past decade, and understand the requirements for future research necessary to realize the practical applications of all-solid-state lithium batteries. To date, research on all-solid-state lithium batteries has focused on achieving overpotential properties similar to those of conventional liquid-lithium-ion batteries by increasing the ionic conductivity of the solid electrolytes. However, the increase in the ionic conductivity should be accompanied by improvements of the electronic conductivity within the electrode to enable practical applications. This essay provides a critical overview of the recent progress and future research directions of the all-solid-state lithium batteries for practical applications

Proprioceptive External Torque Learning for Floating Base Robot and its Applications to Humanoid Locomotion

The estimation of external joint torque and contact wrench is essential for achieving stable locomotion of humanoids and safety-oriented robots. Although the contact wrench on the foot of humanoids can be measured using a force-torque sensor (FTS), FTS increases the cost, inertia, complexity, and failure possibility of the system. This paper introduces a method for learning external joint torque solely using proprioceptive sensors (encoders and IMUs) for a floating base robot. For learning, the GRU network is used and random walking data is collected. Real robot experiments demonstrate that the network can estimate the external torque and contact wrench with significantly smaller errors compared to the model-based method, momentum observer (MOB) with friction modeling. The study also validates that the estimated contact wrench can be utilized for zero moment point (ZMP) feedback control, enabling stable walking. Moreover, even when the robot's feet and the inertia of the upper body are changed, the trained network shows consistent performance with a model-based calibration. This result demonstrates the possibility of removing FTS on the robot, which reduces the disadvantages of hardware sensors. The summary video is available at https://youtu.be/gT1D4tOiKpo.Comment: Accepted by 2023 IROS conferenc

Surface and Interfacial Chemistry in the Nickel-Rich Cathode Materials

With increasing demands for high energy lithium-ion batteries, layered nickel-rich cathode materials have been considered as the most promising candidate due to their high reversible capacity and low cost. Although some of the materials with nickel contents <= 60 % were commercialized, there are tremendous obstacles for further improvement of electrochemical performance, which is strongly related to the unstable cathode surface and interfacial properties. In this regard, a specific review on the interfacial chemistry between the cathode and electrolyte during electrochemical testing is provided. We highlight the underpinning interfacial chemistry and degradation mechanisms of the cathode materials. Finally, light is shed on the recent efforts for enhancing the interfacial stability of the nickel-rich cathode materials

Experimental Study on Development of Mooring Simulator for Multi Floating Cranes

In this study, the coupled motion of a mooring system and multifloating cranes were analyzed. For the motion analysis, the combined equations of motions of the mooring line and multifloating cranes were introduced. The multibody equations for floating cranes were derived from the equations of motion. The finite element method (FEM) was used to derive equations to solve the stretchable catenary problem of the mooring line. To verify the function of mooring simulator, calculation results were compared with commercial mooring software. To validate the analysis results, we conducted an experimental test for offshore operation using two floating crane models scaled to 1:40. Two floating crane models and a pile model were established for operation of uprighting flare towers. During the model test, the motion of the floating cranes and tensions of the mooring lines were measured. Through the model test, the accuracy of the mooring analysis program developed in this study was verified. Therefore, if this mooring analysis program is used, it will be possible to perform a mooring analysis simulation at the same time as a maritime work simulation

Building High-Rate Nickel-Rich Cathodes by Self-Organization of Structurally Stable Macrovoid

Nickel-rich materials, as a front-running cathode for lithium-ion batteries suffer from inherent degradation issues such as inter/intragranular cracks and phase transition under the high-current density condition. Although vigorous efforts have mitigated these current issues, the practical applications are not successfully achieved due to the material instability and complex synthesis process. Herein, a structurally stable, macrovoid-containing, nickel-rich material is developed using an affordable, scalable, and one-pot coprecipitation method without using surfactants/etching agents/complex-ion forming agents. The strategically developed macrovoid-induced cathode via a self-organization process exhibits excellent full-cell rate capability, cycle life at discharge rate of 5 C, and structural stability even at the industrial electrode conditions, owing to the fast Li-ion diffusion, the internal macrovoid acting as "buffer zones" for stress relief, and highly stable nanostructure around the void during cycling. This strategy for nickel-rich cathodes can be viable for industries in the preparation of high-performance lithium-ion cells

Advances and Prospects of Sulfide All-Solid-State Lithium Batteries via One-to-One Comparison with Conventional Liquid Lithium Ion Batteries

Owing to the safety issue of lithium ion batteries (LIBs) under the harsh operating conditions of electric vehicles and mobile devices, all-solid-state lithium batteries (ASSLBs) that utilize inorganic solid electrolytes are regarded as a secure next-generation battery system. Significant efforts are devoted to developing each component of ASSLBs, such as the solid electrolyte and the active materials, which have led to considerable improvements in their electrochemical properties. Among the various solid electrolytes such as sulfide, polymer, and oxide, the sulfide solid electrolyte is considered as the most promising candidate for commercialization because of its high lithium ion conductivity and mechanical properties. However, the disparity in energy and power density between the current sulfide ASSLBs and conventional LIBs is still wide, owing to a lack of understanding of the battery electrode system. Representative developments of ASSLBs in terms of the sulfide solid electrolyte, active materials, and electrode engineering are presented with emphasis on the current status of their electrochemical performances, compared to those of LIBs. As a rational method to realizing high energy sulfide ASSLBs, the requirements for the sulfide solid electrolytes and active materials are provided along through simple experimental demonstrations. Potential future research directions in the development of commercially viable sulfide ASSLBs are suggested. ?? 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinhei

A highly stabilized nickel-rich cathode material by nanoscale epitaxy control for high-energy lithium-ion batteries

Advanced surface engineering of nickel-rich cathode materials greatly enhances their structural/thermal stability. However, their application into lithium-ion full-cells still faces challenges, such as the unstable solid electrolyte interphase (SEI) layer on the anode. Herein, we reveal that the degradation of battery cycle life is caused by the release of divalent nickel ions from the LiNi0.8Co0.1Mn0.1O2 cathode and the formation of nickel metal particles on the graphite anode surface, deteriorating the anode SEI layer and its structural integrity. On the basis of this finding, we demonstrate a stable lithium-ion battery by modifying the cathode surface by creating a nanostructured stabilizer with an epitaxial structure that enhances the morphological robustness. During cycling, the nickel defects in the cathode are significantly suppressed, preventing nickel ion crossover. In particular, the anode SEI layer maintains a uniform and dense structure, leading to outstanding cycling stability in the full-cell with a capacity retention of approximate to 86% after 400 cycles at 25 degrees C

Boosting Reaction Homogeneity in High-Energy Lithium-Ion Battery Cathode Materials

Conventional nickel-rich cathode materials suffer from reaction heterogeneity during electrochemical cycling particularly at high temperature, because of their polycrystalline properties and secondary particle morphology. Despite intensive research on the morphological evolution of polycrystalline nickel-rich materials, its practical investigation at the electrode and cell levels is still rarely discussed. Herein, an intrinsic limitation of polycrystalline nickel-rich cathode materials in high-energy full-cells is discovered under industrial electrode-fabrication conditions. Owing to their highly unstable chemo-mechanical properties, even after the first cycle, nickel-rich materials are degraded in the longitudinal direction of the high-energy electrode. This inhomogeneous degradation behavior of nickel-rich materials at the electrode level originates from the overutilization of active materials on the surface side, causing a severe non-uniform potential distribution during long-term cycling. In addition, this phenomenon continuously lowers the reversibility of lithium ions. Consequently, considering the degradation of polycrystalline nickel-rich materials, this study suggests the adoption of a robust single-crystalline LiNi(0.8)Co(0.1)Mn(0.1)O(2)as a feasible alternative, to effectively suppress the localized overutilization of active materials. Such an adoption can stabilize the electrochemical performance of high-energy lithium-ion cells, in which superior capacity retention above approximate to 80% after 1000 cycles at 45 degrees C is demonstrated

Floatable photocatalytic hydrogel nanocomposites for large-scale solar hydrogen production

Storing solar energy in chemical bonds aided by heterogeneous photocatalysis is desirable for sustainable energy conversion. Despite recent progress in designing highly active photocatalysts, inefficient solar energy and mass transfer, the instability of catalysts and reverse reactions impede their practical large-scale applications. Here we tackle these challenges by designing a floatable photocatalytic platform constructed from porous elastomer-hydrogel nanocomposites. The nanocomposites at the air-water interface feature efficient light delivery, facile supply of water and instantaneous gas separation. Consequently, a high hydrogen evolution rate of 163 mmol h(-1) m(-2) can be achieved using Pt/TiO2 cryoaerogel, even without forced convection. When fabricated in an area of 1 m(2) and incorporated with economically feasible single-atom Cu/TiO2 photocatalysts, the nanocomposites produce 79.2 ml of hydrogen per day under natural sunlight. Furthermore, long-term stable hydrogen production in seawater and highly turbid water and photoreforming of polyethylene terephthalate demonstrate the potential of the nanocomposites as a commercially viable photocatalytic system. Floatable hydrogel nanocomposites, with facile intercalation of various photocatalysts, effectively produce hydrogen. The easily scalable nature of the nanocomposites demonstrates the practical application of this new type of photocatalytic platform.N